Iron concentrations
An attempt was made to correlate
different intensities of luminescence on the scanned CL photographic images
with trace-element concentrations using the electron microprobe.
Detectable amounts of iron, aluminum, and in some cases, titanium were
measured in the vein quartz. Seven electron microprobe traverses
in three samples were performed, measuring the concentration of these trace
elements across the darker-luminescing regions of the quartz near sulfide
crystals. The results clearly indicate a higher concentration of
iron in the darker-luminescing regions next to the sulfide, with the iron
concentration decreasing smoothly away from the sulfide. The dark-luminescing
regions are much wider, ranging up to 140 microns in width, than the expected
width of interaction effects of the electron microprobe, which would be
less than 10 microns. Two traverses were repeated using a lower accelerating
voltage (10 keV compared to 15 keV for the first traverses) to make sure
the iron detected was not due to excitation of iron Ka x-rays in the nearby
sulfides by secondary fluorescence. The weight percent of iron measured
in these traverses was close to that measured during the first traverses,
indicating that the detected iron was not the result of secondary fluorescence.
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