AcknowledgementThis work would not be possible without the support of the National Science Foundation, the Department of Geology, and the University of Maryland.
Summary of Research Interests in the Fields of Granite-Related-Ore- and Hydrothermal Systems
Our research involves physico-chemical experimentation and mass transfer and thermodynamic modeling of the distribution of copper, silver, gold, bismuth, zinc, arsenic, manganese, chlorine, sulfur and other elements among the phases silicate melt, brine, vapor, pyrrhotite, magnetite, Fe-S-O melt, silicate minerals, and other phases that are important in magmatic-hydrothermal, sub-volcanic environments. Our aim is to understand the origin of diversity among magmatic-hydrothermal mineral deposits of certain types (e.g. why some porphyry deposits have high Mo/Cu whereas others have high Au/Cu), and the nature of the magmatic controls on the size and composition of these ores. We have also studied the fundamental properties and reactions of chrysotile asbestos, and related substances, under a wide set of conditions.
MASS TRANSFER AND THERMODYNAMIC MODELING
We have developed a chemical and physical model for progressive devolatilization of both vapor and brine from crystallizing silicate melts. The model is unique in its ability to simulate the partitioning of any number of elements among melt, vapor, brine and crystalline phases simultaneously, accounting for inter-element effects (e.g., how the concentration of HCl in the magmatic volatile phase affects the concentration the FeCl2 or CuCl in a magnetite-saturated magmatic system at a given f(O 2 ) ,T, and P). The modeling suggests chemical conditions that maximize the likelihood of ore formation for a given ore metal, and for a given set of extensive and intensive variables. Models of metal and HCl partitioning can be used to predict the concentration of non-sulfurous components in a geothermal (or ore-generative) magmatic - hydrothermal fluid at its source, and, by considering fugacities of sulfur and oxygen, can be used to predict model compositions of the hydrothermal fluids. We are also continually exploring the proper thermodynamic formulation of ore metal partitioning equilibria.
HIGH TEMPERATURE HYDROTHERMAL AND RELATED EXPERIMENTATION
Experiments ongoing in our lab or in collaboration with other labs include:
· the partitioning of As among the phases melt, vapor and brine at 800oC and 100 – 150MPa
· the partitioning of Ag among the phases pyrrhotite, magnetite, dry rhyolitic melt, and Fe-S-O melt at temperatures above 1000oC.
· Cu partitioning between melt, vapor and brine in the presence of sulfur and chlorine at magmatic conditions
· diamond cell studies of granitic melt and hydrothermal reactions
· partitioning of Bi in magmatic systems at 800oC and 100 MPa
· diamond cell and 0.1 MPa studies of the rate of chrysotile deocomposition
Field work is a necessary component of our work in the LMDR. We have ongoing research in Yosemite National Park, and other areas of the Sierra Nevada, studying the textures and structures of granitic dikes. The object of this study is to elucidate the relationship among the processes of crystallization, volatile phase exsolution and textural development in high level granitic magma chambers.