The following is modified from a letter from Gordon L. Nord, Jr. (USGS) to the granite-research news group on 11 January 1996.
Dear blue-quartz readers, In a study on very blue quartz found in the Roseland charnockites of central Virginia I found the following in a thin section of quartz that graded from blue to white. (1) The blue color of the quartz is seen only in reflection and is red-brown in transmission. This is observed by eye looking at a rather thick polished thin section in natural light. (2) In the petrographic microscope both the blue and white areas contained rutile needles. Also a fine dusting of particles was visible in the blue quartz at the highest magnifications. (3) The concentration of TiO2 and FeO in the blue quartz as determined by the probe was only twice that of background. (4) An ATEM study of the blue quartz showed disk-shaped particles approximately 100 nm thick and 1 um in diameter. EDS showed the presence of Fe and Ti in the particles. Selected area diffraction confirmed that the particles were ilmenite. (5) The density of particles per unit area was less in the white quartz. The backscattering of blue and the forward scattering of red along with the presence of abundant high refractive index particles in the size range of 1/4 of the wavelength of light confirms "Raleigh Scattering" as the mechanism for the blue color in the Roseland Charnockites. The Llanite blue quartz has a shiller which results from a common orientation of the particles (ilmenite has been suggested) as in moonstones. An easy test for "Raleigh Scattering" is the reflection/transmission test as in blue sky and red sunset. Cheers, Gordon Gordon L. Nord Jr. 959 National Center U. S. Geological Survey Reston, VA 22092 Office: 703-648-6745 FAX: 703-648-6789 gnord@mactem.er.usgs.gov